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产品基本信息
产品编号：B387070
产品名称：(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)
产品CAS：128544-05-8
规格含量：50mg
产品价格：面议
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产品详细介绍
标准品编号:
B387070
名称:
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)
别名:
1,​1,​1-​trifluoro-​Methanesulfonic acid 1,​1'-​(1S)​-​[1,​1'-​binaphthalene]​-​2,​2'-​diyl ester; trifluoro-Methanesulfonic acid (1S)-[1,1'-binaphthalene]-2,2'-diyl ester; trifluoro-Methanesulfonic acid (S)-[1,1'-binaphthalene]-2,2'-diyl ester; (S)-(+)-1,1’-Bi-2-naphthol bis(trifluoromethanesulfonate); (S)-2,2’-Bis(trifluoromethanesulfonyloxy)-1,1'-binaphthalene; (S)-2,2’-Bis(trifluoromethanesulfonyloxy)-1,1'-binaphthyl; (S)-BINOL bis(triflate)
CAS号:
128544-05-8
分子式:
C₂₂H₁₂F₆O₆S₂
分子量:
550.45
类别:
Building Blocks; Miscellaneous;
应用:
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl bis(trifluoromethanesulfonate) is a useful building block used in the synthetic preparation of polyketones. It also coordinates to Pd(0) metal centers to form a catalyst used in the C-H activation and cyclization of ketene aminal phosphates.
文献
Liu, J.; et al.: Org. Lett., 19, 5593 (2017); Grosheva, D.; et al. ACS Catal., 7, 7417 (2017).
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