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产品基本信息
产品编号：B415150
产品名称：(R,R)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) Chlor
产品CAS：138124-32-0
规格含量：50g
产品价格：面议
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产品详细介绍
标准品编号:
B415150
名称:
(R,R)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) Chloride
别名:
Jacobsen's Catalyst; Chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese; (-)-Chloro{(1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III); [SP-5-13-(1R-trans)]-Chloro[[2,2'-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese; Chloro[[2,2'-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N',O,O']manganese; (SP-5-13)-Chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese;
CAS号:
138124-32-0
分子式:
C₃₆H₅₂ClMnN₂O₂
分子量:
635.2
种类:
Building Blocks; Chiral Molecules;
应用:
(R,R)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) Chloride is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.
文献
Tavadyan, L.A., et al.: Int. J. Chem. Kinetics., 369, 431 (2007); Hamasaki, A.. et al.: Adv. Syn. Catalys., 354, 2129 (2012);
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