2,3,4-Triacetate 6-O-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-β-D-glucopyranose is an intermediate in the synthesis of Guaiacol-beta-D-gentiobioside (G245570), which is a Guaiacol Conjugate, that has shown to present in fermentation of grapes that had been exposed to bushfire smoke and can potentially yield unpalatable, smoke-affected wine.