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产品编号：B430395
产品名称：[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
产品CAS：130004-33-0
规格含量：250mg
产品价格：面议
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产品详细介绍
标准品编号:
B430395
名称:
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
别名:
[1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride; (S)-[[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]-P,P']chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride; (S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine Ruthenium Complex; ((S)-(2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl))(chloro)(η6-p-isopropyltoluene)ruthenium(1+) Chloride; ((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)(chloro)(η6-4-isopropyltoluene)ruthenium(1+) Chloride; [(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride
CAS号:
130004-33-0
分子式:
C₅₄H₄₆Cl₂P₂Ru
外观：
Brownish Yellow Solid
熔点:
>160°C (dec.)
分子量:
928.87
储存:
Hygroscopic, 冰箱保存, under inert atmosphere
溶解度:
Chloroform (Sparingly)
种类:
Building Blocks; Catalyst; Miscellaneous;
应用:
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride is used as a catalyst in the asymmetric synthesis of UK 370106 (U700620); an MMP-3 inhibitor. It is also highly effective in the hydrogenation of 2-(6'-methoxy-2'-naphthyl)propenoic acid and β-ketoesters.
文献
Ashcroft, C.P., et al.: Org. Process Res. Dev., 7, 362 (2003); Qiu, L., et al.: Org. Lett., 4, 4599 (2002)
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