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产品基本信息
产品编号:C989533
产品名称:1,4-Cyclohexadiene Monoepoxide
产品CAS:6253-27-6
规格含量:250mg
产品价格:面议
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产品详细介绍
标准品编号:
C989533
名称:
1,4-Cyclohexadiene Monoepoxide
别名:
1,2-Epoxy-4-cyclohexene; 1,4-Cyclohexadiene 1,2-Oxide; 1,4-Cyclohexadiene Monoxide; 4,5-Epoxy-1-cyclohexene; 4,5-Epoxycyclohexene; Cyclohexene 4,5-Epoxide; NSC 116459; NSC 196239;
CAS号:
6253-27-6
分子式:
C₆H₈O
外观:
Clear Colorless Oil
分子量:
96.13
储存:
冰箱保存
溶解性:
Chloroform, Ethyl Acetate
稳定性:
Smelly, Volatile product
种类:
Building Blocks; Miscellaneous;
应用:
1,4-Cyclohexadiene Monoepoxide is a synthetic intermediate. It is used as a reactant in the enantioselective formal synthesis of 4-demethoxydaunomycin. Also used in the asymmetric synthesis of β-amino and vicinal amino alcohols.
参考文献
Sekine, A., et al.: Tetrahedron, 58, 75 (2002); Carree, F., et al.: Org. Lett., 7, 1023 (2005); Arai, K., et al.: J. Am. Chem. Soc., 129, 8103 (2007);