产品基本信息
产品编号：A604065
产品名称：[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-&ka
产品CAS：174813-81-1
规格含量：1g
产品价格：面议
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产品详细介绍
标准品编号:
A604065
名称:
[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium
别名:
[N-[2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-, [S-(R*,R*)]-ruthenium; [S-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]-ruthenium; RuCl[(S,S)-TsDPEN](mesitylene)
CAS号:
174813-81-1
分子式:
C₃₀H₃₃ClN₂O₂RuS
分子量:
622.18
类别:
Building Blocks; Catalyst;
应用:
[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium is a chiral catalyst used for transfer hydrogenation of ketones and imines.
参考:
Fuji, A., et al.: J. Am. Chem. Soc., 118, 2521 (1996); Matsumura, K., et al.: J. Am. Chem. Soc., 119, 8738 (1997); Murata, K., et al.: Org. Lett., 1, 1119 (1999)
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