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产品基本信息
产品编号：B430400
产品名称：[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
产品CAS：134524-84-8
规格含量：250 mg
产品价格：面议
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产品详细介绍
标准品编号:
B430400
名称:
[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
别名:
(SP-4-2)-[(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]dichlororuthenium; [SP-4-2-(S)]-[[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]-P,P']dichlororuthenium; (S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine Ruthenium Complex; (S)-BINAP Dichlororuthenium Complex
CAS号:
134524-84-8
分子式:
C₄₄H₃₂Cl₂P₂Ru
外观：
Dark Brown Solid
熔点:
229-232ºC(dec.)
分子量:
794.65
溶解度:
Chloroform
种类:
Building Blocks; Catalyst; Miscellaneous;
应用:
[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.
文献
Li, Y., et al.: J. Chem. Res-S., no vol., 567 (2002); Makino, K., et al.: Tetrahedron-Asymmetr., 19, 2816 (2008)
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